Chlorophyll & other photosensitives

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Here is where we include the background information on plant photosensitive pigments that is often used to make conclusions on what light wavelengths to include in an ideal LED grow light. For most of you these details are of less interest and you probably just want to know what characteristics to look for in LED plant lights rather than the reasons why they should be included. However, for the more scientifically-minded, we're sure you will appreciate the greater depth behind the conclusions. In general, LED plant lights have to concentrate on catering to the lighting needs of the following photosensitive plant compounds:

Chlorophyll

Chlorophyll A - Chlorophyll A is one of the main photosynthetic pigments found in green plants and absorbs light at a 660nm (red) peak wavelength in the visible light spectrum which is vital for plants. It also has a second peak in the blue region of the spectrum at around 400-450nm.

Chlorophyll B - Chlorophyll B is another of the main photosynthetic pigments found in green plants and like Chlorophyll A, it also has two absorption wavelength peaks in the visible light spectrum but at slightly different wavelengths to those of Chlorophyll A. The light wavelength peaks for Chlorophyll B are located at around a 640nm (red) and at 425-475nm (blue).

Line graph showing the relative amounts of light absoption at different light wavelengths of the photosynthetic pigments, Chlorophyll A and Chlorophyll B

Carotenoids

Carotenoids are a family of pigments that are subdivided into the carotenes and the xanthophylls. They serve two key roles in plants: they absorb light energy for use in photosynthesis, and they protect chlorophyll from photo-damage - their absorption appears to be optimal in the blue regions of the light spectrum within the range of 400-500nm.

Line graph showing the relative amount of light absorption for the Carotenoid family of photosynthetic pigments at different light wavelengths

Cryptochromes

Cryptochromes make up a sub-family of flavoproteins that have a variety of plant functions, such as maintaining plant rhythms and photo-tropism. They absorb light from two regions of the spectrum: blue light (400-500nm) and UV light (sub-400nm range).

Line graph showing the relative amounts of light absorption at different light wavelengths of the photosynthetic pigment family known as the Cryptochromes

Phototropins

Phototropins, like cryptochromes, are another sub-family of flavoproteins that are primarily involved in, you guessed it, photo-tropism, but they also serve other functions in plants as well. Absorption of light occurs at blue wavelengths and they may also absorb from the UV region as well. Although their UV absorption peak is much less defined, protein analysis indicates that they contain a domain in their structure that is responsive to UV, so it is likely to play a role too. Based on this information, we should expect to cater to both its blue (400-500nm) and UV (sub-400nm) wavelengths.

Line graph showing the relative amounts of light absorption at different light wavelengths by the photosynthetic pigment family known as the Phototropins

Phytochromes

Finally we have the phytochromes which absorb in the red (Pr) and far-red (Pfr) portions of the light spectrum. So we need to cater to 600-700nm (red) and 700-800nm (far-red) wavelengths. Phytochromes appear to have several different roles in plants but one role in particular, that of shade avoidance has been well documented: Far-red light has a greater ability to pass though leaves than does red light. As a result of this, leaves lower down receive a higher far-red light-to-red light ratio compared with leaves that have an unobstructed view of sunlight. Consequently, this acts as a signal that they are being overshadowed by other leaves and they will move/grow to try to get a better 'view' of the available sunlight.

Line graph showing the relative amounts of light absorption at different light wavelengths by the photosynthetic pigment family known as the Phytochromes

Conclusion

Photosensitive Pigments
Known Functions
Chlorophyll A & B
photosynthesis
Carotenoids
photosynthesis, photo-protection
Cryptochromes
endogenous rhythms, organ orientation, stem elongation, stomatal opening, germination leaf expansion, root growth, phototropism, flowering induction
Phototropins
phototropism, stomatal opening, chloroplast movement, leaf expansion
Red & Far-Red Phytochrome
leaf expansion, neighbour perception, shade avoidance, stem elongation, seed germination, flowering induction

As you can see from the table, there are quite a few photosensitive pigments found in plants, each participating in different plant functions. We think pretty much every function on the list is desired, so we really should try to cater to them all. Moreover, we must not forget that scientists don't yet know the 'full story', so it is entirely possible that they could discover, later on down the line, that these pigments are playing other critical roles in plant physiology.

Line graph showing the relative amounts of light absorption at different light wavelengths by the photosynthetic pigments found in green plants
Absorption wavelengths of plant photosensitive pigments

UV
blue
green
yellow
orange
red
far-red
Wavelength (nm)
280-400
400-495
495-570
570-590
590-620
620-710
710-850
Chlorophyll A

X

X

Chlorophyll B

X

X
Carotenoids

X



Cryptochromes
X
X



Phototropins
X
X


Red Phytochrome





X

Far-Red Phytochrome


X
In Total: All Pigments
X
X



X
X
Peak absorption wavelengths of plant photosensitive pigments
Plant Pigment



Chlorophyll A

425nm
660nm

Chlorophyll B

470nm
640nm

Carotenoids

470nm & 500nm


Cryptochromes
350nm
450nm


Phototropins
350nm
450nm


Red Phytochrome


660nm

Far-Red Phytochrome


660nm
740nm